Whether you’re cooking dinner or eating it, the knives, spoons, and forks you’re using are probably made of steel. It’s easy to take those utensils for granted, except when they bend, chip, corrode, or lose their sharpness. But how does good cutlery differ from bad, and what compromises are involved in making practical utensils? In this Quick Study, we’ll take a look at the science of steel.
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Steel begins with iron, which, like most metals, is a crystalline solid. A macroscopic piece of room-temperature iron contains many crystalline grains of ferrite—iron atoms arranged in a body-centered cubic lattice. The vast, huge uninterrupted atomic planes in those grains make iron soft. When iron is then subjected to shear stress—that is, when nearby layers are pushed in opposite directions—the atomic planes slide across one another in a process called slip.
When slip occurs in an iron crystal, the crystal’s shape changes forever, and the iron bends permanently That’s fine in a twist tie, not so good in a knife.
Slip is facilitated by two types of crystal flaws known collectively as dislocations . An edge dislocation is the edge of an incomplete atomic plane whose abrupt termination midway through the lattice interrupts the smooth pattern oI planes surrounding it. A screw dislocation has a spiral-staircase character in that a line of atoms circling the dislocation’s axis returns to a different layer . Dislocations reduce the energy barrier that inhibits atomic planes from sliding across one another by allowing the planes to slide piecemeal.
To make iron harder, something must impede the migration of dislocation and thereby curtail slip . One effective technique is to mechanically work the material by pounding it, rolling it, or folding it at modest temperatures so that it develops huge numbers of dislocations, many of which are entangled Entanglement makes the dislocations less mobile, which reduces slip and hardens the iron.
Another winy it harden iron is to add a small amount of carbon to it. The resulting alloy is steel. When alloyed with a few other elements steel can be made to do amazing things.
Carbon is nearly insoluble in ferrite, so adding it to iron dramatically complicates the structure of the resulting steel. The carbon can exist dispersed in the ferrite as a hard iron carbide called cementite, or it can remain in supersaturation within the lattice of a distorted ferrite known as martensite.
The more carbon in the steel (up to about 1% by weight) and the more finely and evenly dispersed the cementite, the more difficult it is for dislocations to move within a grain to facilitate slip and, thus, the harder the steel is . Martensite, which forms when carbon atoms occupying interstitial sites in the ferrite lattice distort the ferrite into a tetragonal crystal, is the hardest steel structure of all and the key ingredient in the cutting edges of the best knives.
But the ability of carbon to make steel much harder than pure iron would be irrelevant if no practical way existed to disperse the cementite in ferrite or to turn ferrite plus carbon into martensite. That’s where temperature enters the picture. When steel containing more than 0.02% carbon by weight is heated above 727 0C, it undergoes a solid—solid phase transition that transforms its body-centered cubic ferrite crystals into face-centered cubic austenite crystals. That subtle phase change can be detected as a slight decrease in volume; austenite is a little denser than ferrite. It’s also detectable magnetically: Ferrite is ferromagnetic below its Curie temperature; austenite never is.
Carbon is far more soluble in austenite than in ferrite. Below 727 0C, steel is mostly carbon-poor ferrite, and virtually all of the steel’s carbon must be accommodated in separated phases of cementite or martensite. But above the threshold temperature at which the ferrite begins to transform into austenite, the excess carbon begins to dissolve into the austenite. Although ferrite, cementite, and austenite phases can coexist at certain temperatures and carbon contents, at temperatures above 912 0C, steel with less than 1% carbon is pure austenite. Part of the shaping required to form knives and utensils is usually done on the hot austenitic steel, which is soft and ductile despite its dissolved carbon.
To disperse cementite throughout the steel or to form martensite, metalworkers heat the steel well above the ferrite-to-austenite transition temperature. They then quench the steel with water, oil, or air so that the austenite quickly transforms back into ferrite and the cementite begins to precipitate out of Solution. The faster and further the steel is cooled, the more finely dispersed the cementite and the harder the steel.
Gently quenched steel yields pearlite, a layered pattern of ferrite and cementite that is strong but not especially hard. It yields too easily to make a good knife edge, but can absorb lots of energy when it bends; utensils with pearlite bodies are extremely sturdy. Moderate quenching gives bainite, considerably harder than pearlite and with a finer, nonlayered pattern. The fastest and deepest quenching produces martensite, which is extremely hard and unyielding—just what a good cutting edge needs.
Deeply quenched steel, however, is brittle. Thermal stresses frozen in the steel, together with [lie intrinsic brittleness of martensite itself, can cause a freshly hardened steel blade to crack spontaneously. To reduce brittleness, metalworkers temper the steel. That is, they reheat it to a few hundred degrees Celsius to allow some crystalline rearrangements, including the precipitation and coalescence of fine iron carbides and the elimination of any remaining small austenite crystals.
Quenched and tempered carbon steel is well-suited to knives and other utensils. Over the centuries blade-smiths have learned how to form and heat-treat carbon steel knives whose bodies are almost unbreakably tough pearlite or bainite and whose martensite cutting edges stay razor .sharp for a long time. Interestingly, ~ some of the greatest steel imp1ements—those of Damascus steel and Toledo steel— involved fabrication techniques that were forgotten and are only now beginning to be rediscovered.
Alloy and stainless steels
Simple carbon steel suffers from two limitations: It requires great skill and care to harden appropriately, and it rusts easily. To make modern alloy steels stronger and easier to harden, they often contain additional elements such as vanadium, titanium, niobium, molybdenum, and chromium. Chromium and nickel can also help prevent rust and corrosion in “stainless” steels.
The added elements in alloy steels play several roles in strengthening and hardening. First, they control growth during heat treatment. Coarse-grained steel is weaker than fine-grained steel because dislocations are more mobile in large grains. The grains in hot, fully austenitie carbon steel recrystallize and grow quickly during treatment. which weakens the steel. Carbides and nitride of niobium and titanium, however, are relatively stable at temperatures, and their presence in the steel throughout it’s heat treatment prevents the grains from growing.
Second, having fine alloy carbides and nitrides dispersed throughout the ferrite grains of the finished cutlery directly blocks the movement of dislocations and impedes slip. Vanadium carbides and nitrides precipitatc during quenching. Chromium and molybdenum act primarily do uring the tempering process, when fine carhides of those two elements form. The process of tempering simple carbon steel causes it to lose some of the hardness it developed during quenching, but tempering steels containing chromium and molybdenum can actually make them harder.
When its chromium content exceeds about 11.5 % by weight, the steel becomes stainless . It develops a thin layer ot chromium oxide on its surface that prevents rusting. Adding nickle further improves its resistance to chemical attack. The most common stainless alloys are about 18% chromium and 8% nickel.
Unfortunately, most stainless steels make poor cutlery because they cannot be hardened thermally . Stainless steels with excessive chromium are ferritic.. That is, they remain ferrite all the way up to their melting points. Stainless steels with execessive nickel, including the common 18-8 recipe, are anstenitic; they remain austenite all the way down to room temperature. Only stainless steels that undergo a ferrite-to-auisleinte transition can be hardened thermally. Those martensitic stainless steels have relatively little nickel and just cnough chromium to make them stainless. They aren’t as impervious to rust or chemical attack as 18-8, but they make much better knives and utensils.
Next time you reach for a knife or fork, just think about the material from which it’s made. Most likely, you’ll be holding a piece of rnartensitic stainless steel, with small ferrite crysrts and martensite, perhaps intermingled with various carbides and nitrides, and wrapped in a thin layer of chromium oxide. It’s an ancient technology tha t gets better every year.
G. Krauss, Steels: Processing, Structure,
ASM International, Materials Park, OH
PHYSICS TODAY Magazine
May 2007 (Pgs. 88-89)
Church of the Science of God
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